Do (pentaarylcyclopentadienyl)molybdenum(VI) dioxo species catalyse alkene epoxidations? Insights from kinetics data.
نویسندگان
چکیده
A (perarylcyclopentadienyl)molybdenum(VI) dioxo complex is shown to catalyse epoxidation of cyclooctene by t-butylhydroperoxide, but decomposition to a much more active non-cyclopentadienyl containing catalyst occurs as the reaction proceeds.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 26 شماره
صفحات -
تاریخ انتشار 2007